Olefin metathesis reactions of sulfur-containing alkenes and dienes

Compound 13a, mg, 1 mmol was dissolved in toluene 5 mL under argon atmosphere.

Olefin Metathesis and Metathesis Polymerization

In the catalytic cycle topthis vinyl carbene first adds to the double bond of the substrate forming a ruthenacyclobutane. Selected papers concerning cross-metathesis, see: Such cycloaddition reactions between two alkenes to give cyclobutanes is symmetry forbidden and occurs only photochemically.

The success of these catalysts stems from their coordinative and electronic unsaturation making them electrophilic and their bulky ligands prevents bimolecular decomposition. Organometallics9, In these cases, propagation is much faster than termination or chain transfer reactions, and with the appropriate catalyst tuning, initiation can be made fast relative to propagation.

As ruthenium carbenes are nowadays catalyst of choice in alkene metathesis and currently also in enyne bond reorganizations, we will focus on this family of catalysts.

Olefin Metathesis General Information The olefin metathesis reaction the subject of Nobel Prize in Chemistry can be thought of as a reaction in which all the carbon-carbon double bonds in an olefin alkene are cut and then rearranged in a statistical fashion: Diver and Anthony J.

Olefin metathesis reactions of sulfur containing alkenes and dienes

Commercially available ruthenium pre-catalysts were obtained from Sigma Aldrich 1a, 1b, 1d or Apeiron Catalysts 1f www. Others also observed that heterogeneous catalysts that were intended to polymerize propylene sometimes generated butenes and a copolymer of propylene and ethylene instead. Then solvent was evaporated and the crude product was purified by flash chromatography c-hexane: When reactions with olefins are performed in the presence of a Lewis base, the intermediate titanium metallacycle can be isolated and even structurally characterized Eq.

The driving force of the reaction is the formation of a thermodynamically stable, conjugated 1,3-diene. The reactivity of these catalysts can be tuned very easily by changing the nature of the alkoxide ligands.

Some of these catalyst systems are placed on an alumina or silica support. However, very useful yields of cross-enyne metathesis products can be obtained, for example, by using an excess of ethylene: The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering.

They are catalyst precursors, or pre catalysts. However, given the challenge of finding a highly active catalyst that can tolerate the functional groups in tires sulfur, carbon black etc.

News Catalysts There have been roughly four distinct generations of olefin metathesis catalysts:The Nobel Prize in Chemistry of was shared by Yves Chauvin, Robert killarney10mile.com and Richard killarney10mile.comk for their contributions to the field of Olefin Metathesis.

Olefin Metathesis [1] involves two olefin substrates which form a four-membered ring intermediate (first proposed by Chauvin) and then rearrange the substituents to form. Issue in Honor of Prof. Siegfried Blechert ARKIVOC (iv) Olefin metathesis reactions of sulfur-containing alkenes and dienes Cezary Samojłowicz and Karol Grela* Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/ Olefin metathesis reactions fall into three broad groups in which the overall chemistry is represented by equations undergoing exchange, ring-opening metathesis polymerization, and ring-closing metathesis.

This can lead to polymer chains containing units formed both by addition to the double bond and by cleavage of the double bond. Download Citation on ResearchGate | Olefin metathesis reactions of sulfur-containing alkenes and dienes | The olefin metathesis reaction of sulfur-containing olefins is a challenging transformation.

There are a wide variety of variants on this reaction as is discussed below.

olefin metathesis

Mechanism. The commonly accepted mechanism for the olefin metathesis reaction was proposed by Chauvin and involves a [2+2] cycloaddition reaction between a transition metal alkylidene complex and the olefin to form an intermediate metallacyclobutane.

This metallacycle. The driving force of the reaction is the formation of a thermodynamically stable, conjugated 1,3-diene. As such reactions are conducted under conditions of dilution that favor the RCEYM over competing cross-alkene metathesis or cross-enyne metathesis, the availability of the methylene is the rate-limiting step.

In addition, the vinyl carbene is .

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Olefin metathesis reactions of sulfur-containing alkenes and dienes
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